Spontaneous ring transformation of a 5-azido-1,2,3-thiadiazole |
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Authors: | Gerrit L abbé,Martine Deketele,Jean-Paul Dekerk |
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Affiliation: | Department of Chemistry, University of Leuven Celestijnenlaan 200F, B-3030 Heverlee, Belgium. |
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Abstract: | The reaction of 4-carbethoxy-5-chloro-1,2,3-thiadiazole () with sodium azide results in the formation of ethyl α-thiatriazolyldiazoacetate () instead of the corresponding azide (). Two plausible mechanisms for this new rearrangement are formulated. |
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