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Spontaneous ring transformation of a 5-azido-1,2,3-thiadiazole
Authors:Gerrit L&#x;abbé  Martine Deketele  Jean-Paul Dekerk
Institution:Department of Chemistry, University of Leuven Celestijnenlaan 200F, B-3030 Heverlee, Belgium.
Abstract:The reaction of 4-carbethoxy-5-chloro-1,2,3-thiadiazole (1) with sodium azide results in the formation of ethyl α-thiatriazolyldiazoacetate (3) instead of the corresponding azide (2). Two plausible mechanisms for this new rearrangement are formulated.
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