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Heterocyclisation de diols βγ′-alleniques.
Authors:Jean-Jacques Chilot  Alain Doutheau  Jacques Gore
Affiliation:Laboratoire de Chimie Organique I, ERA 611 du CNRS, Université Claude Bernard Lyon I,E.S.C.I.L., 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne Cédex France
Abstract:The silver nitrate assisted cyclization of the entitled diols 3 leads, depending on the substitution of the allenic linkage, specifically to dihydropyranes 4, when R is alkyl or to an equimolecular mixture of 4 and its tetrahydrofuranyl isomer 5 when R is hydrogen.
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