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α - Benzenesulfonyl free radicals
Authors:M. Julia  C. Rolando  J.N. Verpeaux
Affiliation:Laboratoire de Chimie de l''Ecole Normale Supérieure 24 rue Lhomond, 75231 Paris, France.
Abstract:Allylic α-halosulfones give, on reduction with tri n-butyl tin hydride, sizeable amounts of dimers. It so appears that free radicals can indeed be formed α to an arenesulfonyl group and coupling can occur during tin hydride reduction of halides.
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