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Nucleophilic participation in the solvolysis of the t-butyldimethylsulfonium ion

Authors:	Dennis N Kevill Wan Ahmad Kamil Steven W Anderson

Institution:	Department of Chemistry, Northern Illinois University DeKalb, Illinois 60115 U.S.A.

Abstract:	Studies with the $t$ -butyldimethylsulfonium ion give evidence for nucleophilic participation in the solvolyses of $t$ -butyl compounds but electrophilic assistance would be the dominant factor for $t$ -butyl chloride solvolysis.

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