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O-silylated enolate phenylthialkylation: A synthesis of α,β-unsaturated 5- and 6-membered lactones.
Authors:Hassan A Khan  Ian Paterson
Institution:Department of Chemistry, University College London, 20 Gordon Street, London WC1H OAJ, England.
Abstract:ZnBr2-catalysed phenylthioalkylation of ketene bis(trimethylsilyl)acetals, obtained from carboxylic acids, with appropriate α-chlorosulphides can be used to prepare γ- and δ- lactones.
Keywords:
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