Regioreversed reactions of trimethylsilyl or phenylselenyl allylic carbanion with carbonyl compounds via allylic aluminum “ate” complexes |
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| Authors: | Yoshinori Yamamoto Yoshikazu Saito Kazuhiro Maruyama |
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| Affiliation: | Department of Chemistry, Faculty of Science, Kyoto University Kyoto 606, Japan |
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| Abstract: | Triethylaluminum “ate” complexes of trimethylsilyl and phenylselenyl allylic carbanion react with carbonyl compounds at the α-position either exclusively or predominantly. |
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