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Synthesis of (±)-1-desoxy-2-lycorinone and of a possible trans-dihydro-lycoricidine precursor
Authors:Thomas Weller  Dieter Seebach
Institution:Laboratorium für Organische Chemie der Eidgenössischen Technischen Hochschule, ETH-Zentrum, Universitätstrasse 16, CH-8092 Zürich Switzerland
Abstract:En-route from the 5-aryl-3-hydroxy-4-nitro-cyclohexanones 1 and 2, readily available from poly-enolates and 3.4-methylenedioxy-w-nitro-styrene, to dihydro-lycoricidine 3 and to lycorine 4, respectively, the title compounds 9 and 14 are prepared in few steps.
Keywords:
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