The effect of ultrasound on the solvolysis of 2-chloro-2-methylpropane in aqueous alcoholic media |
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Authors: | Timothy J Mason John P Lorimer B.P Mistry |
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Affiliation: | Department of Applied Chemistry, Coventry (Lanchester) Polytechnic, Coventry CVI 5FB England |
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Abstract: | The effect of ultrasonic irradiation (45KHz at 25°C) on the solvolysis of -butyl chloride in aqueous ethanol, -propanol and -butanol is (1) to increase the rate constants in the more alcoholic media and (2) to reduce the m values of these reactions. |
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