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Reduction of sulfonic acids with phosphorus pentasulfide
Authors:Shigeru Oae  Hideo Togo
Affiliation:Department of Chemistry, The University of Tsukuba, Sakura-mura, Ibaraki-ken 305 Japan
Abstract:Arene, and alkanesulfonic acids are easily reduced to the corresponding polysulfides R-(S)n-R (n=2.9≈3.3) by treatment with phosphorus pentasulfide. In this reaction, the formation of both POS and PSH linkages is considered to be involved in the key step of the reduction.
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