Cyclization of α-haloamide with internal double bond by use of the low-valent metal complex |
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Authors: | Miwako Mori Izumi Oda Yoshio Ban |
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Affiliation: | (Faculty of pharmaceutical Sciences, Hokkaido University, Sapporo 060 Japan |
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Abstract: | The α-haloamide having internal double bond was allowed to react with a catalytic amount of Pd(PPh3)4 in the presence of proton sponge to produce a cyclized product in a fairly good yield possibly through the intermediation of σ-alkylmetal complex although it was not isolated. |
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