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Biosynthesis of PR toxin by Penicillium roqueforti, Part 2 evidence for an hydride shift from 2H N.M.R. spectroscopy
Authors:Charles P Gorst-Allman  Pieter S Steyn
Institution:National Chemical Research Laboratory, Council for Scientific and Industrial Research, P.O. Box 395, Pretoria 0001, South Africa
Abstract:The biosynthesis of the eremophilane sesquiterpenoid PR toxin is shown to involve an 1,2-hydride migration from C(5) to C(4) of the molecule.
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