Sequential trapping of dichlorocarbene and dichlorocarbonyl ylides |
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Authors: | Harpal S. Gill John A. Landgrebe |
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Affiliation: | Department of Chemistry, University of Kansas, Lawrence, KS 66045 U.S.A. |
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Abstract: | The thermal decomposition of phenyl (bromodichloromethyl)-mercury in the presence of aryl aldehydes and dimethyl acetylenedicarboxylate leads to the formation of dimethyl 2-halo-5-arylfuran-3, 4-dicarboxylates by selective trapping of the intermediate dihalocarbonyl ylides. |
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