Anti,anti acetals : Photoelectron spectroscopy of trans-1,8-dioxadecalins |
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| Authors: | Flemming S J?rgensen Leif ?rskov-Lauritsen |
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| Institution: | Department of General and Organic Chemistry, The H. C. ?rsted Institute, University o Copenhagen, DK-2100 Copenhagen ?, Denmark |
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| Abstract: | The anti,anti acetals trans-1,8-dioxadecalin and trans-1,8-dioxa-4,5-dithiadecalin have been studied by photoelectron spectroscopy, and the electronic structure of the anti,anti acetal moiety was further elucidated by molecular orbital calculations on dimethoxymethane and visualized by stereoscopic drawings of the frontier orbitals. |
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