Absolute configuration of eldanolide,the wing gland pheromone of the male African sugar cane borer,Eldana saccharina (Wlk.) syntheses of its (+) and (−) enantiomers. |
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Authors: | JP Vigneron R Méric M Larchevêque A Debal G Kunesch P Zagatti M Gallois |
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Institution: | Collège de France, 11 Place Marcelin Berthelot, 75005 Paris, France;Ecole Normale Supérieure, 24 rue Lhomond, 75231 Paris Cedex 05 France;Laboratoire des Médiateurs Chimiques, Domaine de Brouessy, Magny-les-Hameaux, 78470 Saint-Rémy-lès-Chevreuse (CNRS/INRA) France |
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Abstract: | Eldanolide , a novel terpenoid lactone pheromone, was shown to have (3S,4R) configuration by synthesis of both enantiomers and comparison of their CD with the natural pheromone. |
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