New highly strained bridgehead imines, 2-azaadamant-1-ene and 4-azaprotoadamant-3-ene |
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Authors: | Tadashi Sasaki Shoji Eguchi Takashi Okano |
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Affiliation: | Institute of Applied Organic Chemistry, Faculty of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464, Japan |
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Abstract: | An azaanalog of adamantene, 2-azaadamant-1-ene () and 4-azaprotoadamant-3-ene () were generated in the nonstatistical ratio via photolysis of 3-azidonoradamantane (). The highly strained and could not be isolable but were trapped by MeOH. Acidolysis of was also reported, and discussed in comparison with the photolysis. |
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