Concerning the optimum scaling of the inductive substituent constants in substituted benzene reactivities. Aspects from the analysis of quinuclidine basicities |
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Authors: | Yuho Tsuno Mizue Fujio Masami Sawada Yasuhide Yukawa |
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Affiliation: | Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Fukuoka 812, Japan;The Institute of Scientific and Industrial Research, Osaka University, Suita, Osaka 565. Japan |
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Abstract: | Grob's basicity data sets of 4-substituted quinuclidines are successfully correlated with the LArSR Eq. 1, the correlation parameters of which indicate that the inductive substituent constants involved in δop just correspond to 0.74°I. |
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