Phytochemical study on American plants I. Two new phenol glucosides,together with known biflavones and diterpene,from leaves of Juniperus occidentalis Hook |
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Authors: | Nakanishi Tsutomu Inatomi Yuka Murata Hiroko Iida Naoki Inada Akira Lang Frank A Murata Jin |
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Institution: | Faculty of Pharmaceutical Sciences, Setsunan University, Hirikata, Osaka, Japan. nakanisi@pharm.setsunan.ac.jp |
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Abstract: | Two new phenol glucosides termed juniperosides I (1) and II (2) were isolated, together with known two biflavones, cupressuflavone and amentoflavone and a diterpene, 3beta-hydroxy sandaracopimaric acid, from leaves of Juniperus occidentalis HOOK. (Cupressaceae) collected in Oregon, U.S.A., and their structures were established as (1S)- and (1R)-1-(2'-hydroxy-6'-methylphenyl)ethanol 2'-O-beta-D-glucopyranosides (1, 2), respectively, on the basis of spectral, chemical, and synthetic evidence. The glycosides 1 and 2, as well as the corresponding aglycones 1a and 2a, are apparently novel types of naturally occurring compounds; to our knowledge, isolation of these types of natural phenol derivatives has only rarely been reported from the vegetable kingdom. |
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