Preferential carbene insertion into Ge-H vs. other heavier group 14 hydrides via samarium carbenoids |
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| Authors: | Kondo Hitoshi Yamanoi Yoshinori Nishihara Hiroshi |
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| Institution: | Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Tokyo 113-0033, Japan. |
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| Abstract: | The relative reactivities of Zn, Al, and Sm carbenoids in the chemoselective carbene insertion reaction of heavier group 14 hydrides were studied. By variation of the reaction protocols using Sm carbenoids, insertion reaction can favour the Ge-H bonds to give Ge-alkylated derivatives in good to high yield. |
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