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| Open-framework Borophosphate:(NH4)_(0.5)Fe~II_(0.5)Fe~III_(0.5)(H_2O)_2BP_2O_8·0.5H_2O | |
| 作者姓名： | Heng Zhen SHI Yong Kui SHAN* Li Yi DAI Yu Yan LIU |
| 作者单位： | Heng Zhen SHI1，2，Yong Kui SHAN1*，Li Yi DAI1，Yu Yan LIU2 1Department of Chemistry，2Laboratory for Quantum Optics of National Education Commission，East China Normal University，Shanghai 200062 |
| 摘 要： | We are investigating the synthesis and properties of a new class of open framework borophosphate solids with the goal of being able to use in optical devices and magnetic materials. Only a few open-framework ferric borophosphate compounds with a chiral tetraheda-tetraheda helices, KFe(H2O)2BP2O8)H2O(1), Fe(H2O)2BP2O8H2O(2), (NH4)0.4-FeII0.55FeIII0.5(H2O)BP2O8]0.6H2O(3) have been reported by Boy et al.1, Ylmaze et al.2 and Huang and Schfer et al.3. However, Huang and Schfer et… |
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