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Thermal characterization of rubberwood-polymer composites
Affiliation:1. C2MA, Ecole des mines d’Alès, F-30319 Alès, France;2. FEMTO-ST UMR6174, Univ. Bourgogne Franche-Comté, F-25000 Besançon, France;3. DRIVE EA1859, Univ. Bourgogne Franche-Comté, F-58000 Nevers, France;1. The State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China;2. Engineering Research Center of Marine Biological Resource Comprehensive Utlization, Third Institute of Oceanography, State Oceanic Administration, Xiamen 361000, China;1. Materials Science and Engineering Program, School of Engineering and Technology, Walailak University, Thasala District, Nakhon Si Thammarat 80160, Thailand;2. Petrochemical and Polymer Program, School of Engineering and Technology, Walailak University, Thasala District, Nakhon Si Thammarat 80160, Thailand;3. Materials Science and Innovation Program, College of Graduate Studies, Walailak University, Thasala District, Nakhon Si Thammarat 80160, Thailand;1. Department of Wood Science and Paper Technology, Karaj Branch, Islamic Azad University, Karaj, Iran;2. Department of Wood Science and Paper Technology, Chalous Branch, Islamic Azad University, Chalous, Iran;3. Department of Wood Mechanics and Technology, Forestry Faculty, Karadeniz Technical University, 61080 Trabzon, Turkey;4. Department of Wood Mechanics and Technology, Forestry Faculty, Istanbul University, Bahcekoy, Sariyer, 34473 Istanbul, Turkey
Abstract:The thermal properties of five types of radiation-induced wood-polymer composites based on a tropical hardwood, rubberwood (Hevea braziliensis), was studied by oxygen index measurement, differential thermal analysis (DTA) and thermogravimetry (TG). The DTA and TG curves of composites were different from those of rubberwood, which can be attributed to the presence of the incorporated polymers. Of the five composites, the one impregnated with bis(2-chloroethyl)vinyl phosphonate reduced the initial temperature of decomposition, increased the peak temperatures of exothermic reactions, and increased the char yield. Comparison with physical blends of rubberwood and the corresponding polymer provided some evidence of chemical interaction of wood and polymer in some of the composites.
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