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Chemical properties of anion vacancies on zinc oxide
Authors:W.H. Cheng  H.H. Kung
Affiliation:Department of Chemical Engineering, the Materials Research Center, and the Ipatieff Catalytic Laboratory, Northwestern University, Evanston, Illinois 60201, USA
Abstract:A ZnO(404̄1) surface, which is a stepped [4(101̄0) × (0001)] surface containing a high density of anion vacancies was prepared. When compared with the nonpolar (101̄0) surface, the (404̄1) surface adsorbed O2 and methanol more strongly, but CO2 more weakly. The decomposition products of methanol were different on these two surfaces.
Keywords:To whom correspondence should be sent.
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