| 两亲性卟啉的合成及其L—B膜 |
| |
| 引用本文： | 文珂 曹锡章. 两亲性卟啉的合成及其L—B膜[J]. 应用化学, 1992, 9(3): 70-71 |
| |
| 作者姓名： | 文珂 曹锡章 |
| |
| 作者单位： | 吉林大学化学系，吉林大学化学系 长春 130023，长春 130023 |
| |
| 摘 要： | 早期L-B膜的研制主要着眼于长碳链脂肪酸及其衍生物。近来,由于对膜性能的特殊要求,人们把注意力转向丁二炔、酞菁和卟啉衍生物。本文用四一(N,N-二甲基氨基苯基)卟啉(TDMAPP)与溴代十六烷反应得到两亲性的含有4个长碳链的澳化四-(4-
|
| 关 键 词： | 卟啉衍生物 合成 L－B膜 |
| 收稿时间： | 1991-05-05 |
SYNTHESES OF AMPHIPHILIC PORPHYRINS AND THEIR LANGMUIR-BLODGETT FILMS |
| |
| Wen Ke,Cao Xizhang. SYNTHESES OF AMPHIPHILIC PORPHYRINS AND THEIR LANGMUIR-BLODGETT FILMS[J]. Chinese Journal of Applied Chemistry, 1992, 9(3): 70-71 |
| |
| Authors: | Wen Ke Cao Xizhang |
| |
| Abstract: | Tetra-(N,N-dimethylaminophenyl)porphyrin(TDMAPP) reacts with n-C_(16)H_(33)Br to give quaternary bromides of the amphiphilie porphyrin containing four long aliphatic chains. Its Cu, Zn and Co complexes have been prepared. These porphyrins are capable of forming Langmuir-Blodgett films. The UV-Visible spectra of the L-B films as well as of the solid compounds indicate that the interations between molecules in two cases are different. |
| |
| Keywords: | long chain porphyrin derivative synthesis L-B film |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《应用化学》浏览原始摘要信息 |
|
点击此处可从《应用化学》下载全文 |
