| 二(甲基环戊二烯基)二苯氧基钛的合成与性能研究 |
| |
| 引用本文： | 吴绍祖,周耀坤.二(甲基环戊二烯基)二苯氧基钛的合成与性能研究[J].高等学校化学学报,1983,4(1):123. |
| |
| 作者姓名： | 吴绍祖 周耀坤 |
| |
| 作者单位： | 兰州大学化学系 |
| |
| 摘 要： | Wilkinson等1]采用所谓经典的方法,制得二(甲基环戊二烯基)二氯化钛(Ⅰ),产率只有26%。Brantley2]用TiCl4和相应的格氏试剂反摩也制得了该化合物,但操作条件较苛刻,产率未见报导。
|
| 收稿时间： | 1981-07-10 |
STUDIES ON SYNTHESIS AND REACTIVITY OF BIS(METHYLCYCLOPENTADIENYL) TITANIUM DIPHENOXIDE |
| |
| Wu Shaozu,Zhou Yaokun.STUDIES ON SYNTHESIS AND REACTIVITY OF BIS(METHYLCYCLOPENTADIENYL) TITANIUM DIPHENOXIDE[J].Chemical Research In Chinese Universities,1983,4(1):123. |
| |
| Authors: | Wu Shaozu Zhou Yaokun |
| |
| Institution: | Department of Chemistry, Lanzhou University, Lanzhou |
| |
| Abstract: | A novel method of synthesis of bis(methylcyclopentadienyl) titanium dichloride(Ⅰ) by reacting methylcyclopentadiene with titanium tetrachloride in the presence of diethylamine in tetrahydrofuran has been developed. Bis(methylcyclopentadienyl) titanium diphenoxide(Ⅱ) was synthesized and studied. Compound(Ⅱ) readily reacts with electrophilic reagents, such as hydrogen chloride, acetyl chloride and thionyl chloride, resulting in the cleavage of the oxygen-titanium bond and the formation of compound(Ⅰ). |
| |
| Keywords: | |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
