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Liquid—liquid equilibria for the system water + acetic acid + methyl isoamyl ketone
Authors:M.E. Soares  A.G. Medina  P.J. Bailes
Affiliation:Centro de Engenharia Química, Faculdade de Engenharia, Porto Portugal;Schools of Chemical Engineering, University of Bradford, Bradford, West Yorkshire BD7 1DP Gt. Britain
Abstract:Liquid—liquid equilibrium data obtained over the temperature range 10–60°C for the binary system water + methyl isoamyl ketone (MIAK) are presented together with ternary data for the system water + acetic acid + MIAK at 15, 25 and 40°C. The latter system may be of particular interest for solvent extraction studies, in that MIAK has a flash point much higher than that of methyl isobutyl ketone (MIBK). The new data presented in this paper are correlated in terms of the well-known NRTL and UNIQUAC models. Using the UNIFAC model and the parameter table published recently, experimental results are compared with the predicted values.
Keywords:Author to whom correspondence should be addressed
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