| Fe(III)与两种4-羟基吡啶二酸形成的配合物的合成与晶体结构 |
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| 引用本文： | 高洪苓,张虹,康怀萍,崔建中. Fe(III)与两种4-羟基吡啶二酸形成的配合物的合成与晶体结构[J]. 无机化学学报, 2007, 23(6): 1099-1102 |
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| 作者姓名： | 高洪苓 张虹 康怀萍 崔建中 |
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| 作者单位： | 天津大学化学系，天津 300072,天津大学化学系，天津 300072,河北科技大学化学与药物工程学院，石家庄 050018,天津大学化学系，天津 300072 |
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| 基金项目： | 天津大学校科研和教改项目 |
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| 摘 要： | A iron(III) complex [Fe(2,6-HDA)(2,5-HDA)(H2O)2]·2.5H2O (2,6-HDA=4-hydroxypyridine-2,6-dicarboxylic acid, 2,5-HAD=4-hydroxypyridine-2,5-dicarboxylic acid), has been hydrothermally synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. It belongs to monoclinic system, with space group C2/c, a=0.155 8(4) nm, b=0.215 8(5) nm, c=0.133 0(3) nm, β=125.468(3)°, V=3.641 1(15) nm3, Z=8. The geometry around iron(III) is a distorted pentagonal bipyramid. CCDC: 631130.
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| 关 键 词： | 4-羟基吡啶-2，6-二甲酸； 4-羟基吡啶-2，5-二甲酸； 铁配合物； 晶体结构 |
| 文章编号： | 1001-4861（2007）06-1099-04 |
| 修稿时间： | 2007-01-082007-04-12 |
Synthesis and Crystal Structure of a Complex Derived from Iron(III) and Two Kinds of 4-hydroxypyridine Dicarboxylic Acid |
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| GAO Hong-Ling,ZHANG Hong,KANG Huai-Ping and CUI Jian-Zhong. Synthesis and Crystal Structure of a Complex Derived from Iron(III) and Two Kinds of 4-hydroxypyridine Dicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, 2007, 23(6): 1099-1102 |
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| Authors: | GAO Hong-Ling ZHANG Hong KANG Huai-Ping CUI Jian-Zhong |
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| Affiliation: | Department of Chemistry, Tianjin University, Tianjin 300072,Department of Chemistry, Tianjin University, Tianjin 300072,College of Chemical & Pharmaceutical Engineering, Hebei University of Science & Technology, Shijiazhuang 050018 and Department of Chemistry, Tianjin University, Tianjin 300072 |
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| Abstract: | |
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| Keywords: | 4-hydroxypyridine-2,6-dicarboxylic acid 4-hydroxypyridine-2,5-dicarboxylic acid iron(III) complex crystal structure |
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