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Magneto-structural correlations in Pr0.15Gd0.85Mn2Ge2
Authors:I. Dincer  Y. Elerman  H. Ehrenberg  C. Baehtz
Affiliation:a Ankara University, Faculty of Engineering, Department of Engineering Physics, 06100 Besevler-Ankara, Turkey
b Institute for Materials Science, Darmstadt University of Technology, Petersenstrasse 23, D-64287 Darmstadt, Germany
c Hamburger Synchrotronstrahlungslabor, Notkestr. 85, D-22603 Hamburg, Germany
Abstract:Magneto-structural correlations in Pr0.15Gd0.85Mn2Ge2 have been studied by synchrotron diffraction in the temperature range between 11 and 300 K. This compound crystallizes in the ThCr2Si2-type structure (space group View the MathML source). The unit cell parameters a and c were determined by Rietveld refinements as a function of temperature. Anomalies in the temperature dependence of the unit cell parameters a and c, the c/a ratio and the unit cell volume V at about 240 and 140 K, which is close to the magnetic phase transition temperatures, indicate a pronounced magneto-structural correlation. Spontaneous volume change and linear magnetostrictions are derived as a function of temperature.
Keywords:75.20.En   75.25.z   75.30.Kz   61.10.Nz   75.30.Cr
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