Bis[2‐(2‐hydroxyethyl)pyridinium] μ‐decavanadato‐bis[pentaaquamanganate(II)] tetrahydrate |
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| Authors: | Lenka Kliš tincová ,Erik Rakovský ,Peter Schwendt |
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| Abstract: | The structure of the title compound, (C7H10NO)2[Mn2V10O28(H2O)10]·4H2O or (C5H4NHCH2CH2OH)2[{Mn(H2O)5}2V10O28]·4H2O, at 293 (2) K has triclinic (P) symmetry. The asymmetric unit consists of one half of a decavanadate anion of Ci symmetry, one [Mn(H2O)5]2+ group, one 2‐(2‐hydroxyethyl)pyridinium cation and two solvent water molecules. The decavanadate ion bridges between two [Mn(H2O)5]2+ groups, thus forming a dodecanuclear complex unit. Complex units are connected via a hydrogen‐bonding network, forming supramolecular layers lying in the (001) plane. Cations and solvent water molecules are located between these layers. |
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