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Gallic acid grafted to amine‐functionalized magnetic nanoparticles as a proficient catalyst for environmentally friendly synthesis of α‐aminonitriles
Authors:Ali Maleki  Sepide Azadegan  Jamal Rahimi
Abstract:An effective approach of one‐pot catalytic Strecker reaction between aromatic aldehydes, aniline or toluidine and trimethylsilyl cyanide in the presence of amine‐functionalized Fe3O4@SiO2 nanoparticles grafted with gallic acid (GA) as a powerful catalyst was developed. The fabricated reusable catalyst demonstrated high efficiency in the synthesis of α‐aminonitriles along with facile work‐up procedure. Fe3O4@SiO2‐NH2‐GA was characterized by Fourier transform‐infrared spectroscopy, scanning electron microscopy image, vibrating‐sample magnetometer curve, energy‐dispersive X‐ray analysis and thermogravimetric analysis.
Keywords:aminonitrile  Fe3O4/SiO2 nanocomposite  gallic acid  heterogeneous green nanocatalyst  multi‐component reaction
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