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Fe3O4@SiO2‐copper sucrose xanthate as a green nanocatalyst for N‐, O‐ and S‐arylation
Authors:Iman Radfar  Maryam Kazemi Miraki  Naghmeh Esfandiary  Leila Ghandi  Akbar Heydari
Abstract:Formation of C(sp2)–X bonds was carried out using a Fe3O4@SiO2‐copper(I) sucrose xanthate nanoparticle catalyst with the aid of the copper(I) xanthate moiety in the catalyst which was prepared from the reaction between sucrose and carbon disulfide through an alkaline medium via the traditional Zeise approach. Various techniques were employed for the characterization of these novel nanoparticles. Three sorts of heteroatoms, N, O and S, successfully underwent heteroatom arylation to produce secondary or tertiary amines, ethers and thioethers, respectively.
Keywords:carbon–  heteroatom coupling  copper  sucrose  Ullmann coupling  xanthate
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