| Tween-80胶束萃取硫氰酸钼(Ⅴ)配合物研究 |
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| 引用本文： | 杨桦,李晓燕,张爱丽,曹同川,滕丽曼. Tween-80胶束萃取硫氰酸钼(Ⅴ)配合物研究[J]. 光谱学与光谱分析, 2002, 22(1): 116-117 |
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| 作者姓名： | 杨桦 李晓燕 张爱丽 曹同川 滕丽曼 |
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| 作者单位： | 1. 大连理工大学化工学院,辽宁,大连,116012
2. 天津天士力制药集团有限公司药物研究所,天津,300142 |
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| 摘 要： | 本文研究了用Tween-80作萃取剂取硫氰酸钼（Ⅴ），在0.1%浓度下即可达到94％的萃取率，而同样条件下对硫氰酸钨（Ⅲ）基本不萃取，因此可将二者很好的分离。其萃取机理可能为胶束萃取，属超分子范畴。
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| 关 键 词： | 胶束萃取 硫氰酸钼(Ⅴ) 超分子化学 Tween-80 配合物 非离子表面活性剂 |
| 文章编号： | 1000-0593(2002)01-0116-02 |
| 修稿时间： | 2000-12-14 |
Study on Molybdenum(Ⅴ) Thiocyanate Complex Extracted by Tween-80 |
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| YANG hua ,LI Xiao-yan ,ZHANG Ai-li ,CAO Tong-chuan ,and TENG Li-man .State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian ,China. Study on Molybdenum(Ⅴ) Thiocyanate Complex Extracted by Tween-80[J]. Spectroscopy and Spectral Analysis, 2002, 22(1): 116-117 |
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| Authors: | YANG hua LI Xiao-yan ZHANG Ai-li CAO Tong-chuan and TENG Li-man .State Key Laboratory of Fine Chemicals Dalian University of Technology Dalian China |
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| Affiliation: | State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China. |
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| Abstract: | Molybdenum(V) thiocyanate complex extracted by Tween-80, a non-ionic surface active agent, in chloroform has been studied. When the concentration of Tween-80 is 0.1%, extractive ratio can reach 94%, while tungsten(III) thiocyanate can not extracted in the same condition. Therefore, the two kinds of complexes can be separated very well. It enjoys a better extraction efficiency compared with petroleum ether or dimethyl sulfoxide and the advantage of low cost, no toxicity and no pollution. The extraction mechanism has been studied and may be a kind of extraction belonging to the category of supermolecular, which has not been reported publicly. |
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