On the stereochemistry of photoaddition between α,β-unsaturated ketones and olefins—II |
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| Authors: | Giovanna Marini-Bettòlo Soumya P Sahoo Gerald A Poulton Thomas YR Tsai Karel Wiesner |
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| Institution: | Natural Products Research Center, University of New Brunswick, Fredericton, New Brunswick, Canada E3B 5A3 |
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| Abstract: | Some years ago an empirical rule, which allows the prediction of product stereochemistry in cis-photocycloaddition reactions of α,β-unsaturated ketones and olefins was tentatively proposed. Several additional examples, both selected from the literature and synthesized in our laboratory, seem to strengthen the validity of the rule. |
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