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Interactions of aliphatic β-amino-β-trifluoromethylvinyl ketones with ethylenediamine
Authors:V Ya Sosnovskikh  M Yu Mel'nikov  I A Kovaleva
Institution:(1) A. M. Gorky Ural State University, 51 prosp. Lenina, 620083 Ekaterinburg, Russian Federation
Abstract:The reactions of aliphatic β-amino-β-trifluoromethylvinyl ketones with an excess of ethylenediamine at room temperature afforded the corresponding 2,3-dihydro-1H-1,4-diazepines or substituted 2-acetonyl-2-trifluoromethylimidazolidines (the latter were obtained when the approach to the carbonyl group was sterically hindered). Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2305–2308, November, 1998.
Keywords:aliphatic β  -amino-β  -trifluoromethylvinyl ketones  ethylenediamine  2  3-dihydro-1H-1  4-diazepines  substituted 2-acetonyl-2-trifluoromethylimidazolidines
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