| 氧-硼共修饰多壁碳纳米管载铂催化剂的制备及氧还原活性 |
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| 引用本文： | 薛盛鼎,顾军,韩梦飞,祝苏君,于涛. 氧-硼共修饰多壁碳纳米管载铂催化剂的制备及氧还原活性[J]. 无机化学学报, 2013, 29(18) |
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| 作者姓名： | 薛盛鼎 顾军 韩梦飞 祝苏君 于涛 |
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| 作者单位： | 南京大学物理学院, 南京 210093;南京大学物理学院, 南京 210093;南京东焱科技有限公司, 南京 211100;南通南京大学材料工程技术研究院, 南通 226019;南京大学物理学院, 南京 210093;固体微结构国家实验室, 南京 210093 |
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| 基金项目： | 南通市应用基础研究基金(No.JC2021109)资助。 |
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| 摘 要： | 采用一种简便的方法，合成了氧-硼共修饰的多壁碳纳米管材料，以此为载体制备的铂基催化剂具有更小的铂粒径、更高的电化学表面积(40 m2·gPt-1)和更高的氧还原活性(0.3 A·mgPt-1)。氧、硼在提高碳纳米管的载体分散性、控制铂颗粒的均匀性和粒径、促进氧还原反应的氧吸附/解离方面发挥着重要的作用。
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| 关 键 词： | 催化剂 碳纳米管 铂 硼 氧还原活性 |
| 收稿时间： | 2022-07-22 |
| 修稿时间： | 2022-10-21 |
Preparation of platinum catalysts supported on oxygen-boron co-modification multi-wall carbon nanotubes and their oxygen reducing activity |
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| XUE Sheng-Ding,GU Jun,HAN Meng-Fei,ZHU Su-Jun,YU Tao. Preparation of platinum catalysts supported on oxygen-boron co-modification multi-wall carbon nanotubes and their oxygen reducing activity[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(18) |
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| Authors: | XUE Sheng-Ding GU Jun HAN Meng-Fei ZHU Su-Jun YU Tao |
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| Affiliation: | School of Physics, Nanjing University, Nanjing 210093, China;School of Physics, Nanjing University, Nanjing 210093, China;Nanjing Doinpower Technology Co., Ltd., Nanjing 211100, China;Nantong Institute of Materials Engineering Nanjing University, Nantong, Jiangsu 226019, China; School of Physics, Nanjing University, Nanjing 210093, China;National Laboratory of Solid State Microstructures, Nanjing 210093, China |
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| Abstract: | We synthesized an oxygen-boron co-decorated multi-walled carbon nanotube material by a simple method. After that, it was used as a carrier to prepare platinum-based catalysts and carried out a variety of characterizations. The results indicated that the platinum particles supported on this carrier showed smaller particle size, higher electrochemical surface area (40 m2·gPt-1), and higher oxygen reduction activity (0.3 A·mgPt-1). Predictably, boron and oxygen play an important role in improving the dispersion of carbon nanotubes, controlling the uniformity and size of platinum particles, and promoting oxygen adsorption/dissociation in the oxygen reduction reaction. |
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| Keywords: | catalyst carbon nanotubes platinum boron oxygen-reducing activity |
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