| Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a New Zinc Carboxylate-phosphonate： [Zn3（O3PCH（CH3）COO）2（H2O）] |
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| 引用本文： | LAI Zhu-Zhia,b FU Rui-Biaoa SHENG Tian-Lua LI Ya-Mina HUANG Xi-Hea WU Xin-Taoa② a.Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a New Zinc Carboxylate-phosphonate： [Zn3（O3PCH（CH3）COO）2（H2O）][J].结构化学,2006,25(11):1397-1401. |
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| 作者姓名： | LAI Zhu-Zhia b FU Rui-Biaoa SHENG Tian-Lua LI Ya-Mina HUANG Xi-Hea WU Xin-Taoa② a |
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| 作者单位： | LAI Zhu-Zhia，b FU Rui-Biaoa SHENG Tian-Lua LI Ya-Mina HUANG Xi-Hea WU Xin-Taoa② a (State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China) b (Graduate School of the Chinese Academy of Sciences，Beijing 100039，China) |
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| 基金项目： | 国家重点实验室基金;中国科学院基金;国家自然科学基金;中国科学院自然科学基金;福建省自然科学基金 |
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| 摘 要： | 1 INTRODUCTION Many efforts have been devoted to the synthesis of metal organophosphonates during the past three decades because of their rich variety of structural chemistry as well as their practical or potential applications in the areas of adsorption/desorption1, 2], catalysts3, 4], meso-/microporous materials5～7] and intercalation chemistry8～16]. One encouraging deve- lopment direction is the use of phosphonic acids with bi- and trifunctional groups, such as amino, hydroxyl and…
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| 关 键 词： | 热水合成 单晶结构 锌配合物 羧酸盐-膦酸酯 荧光性质 |
Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a New Zinc Carboxylate-phosphonate: [Zn3(O3PCH(CH3)COO)2(H2O)] |
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| LAI Zhu-Zhi,FU Rui-Biao,SHENG Tian-Lu,LI Ya-Min,HUANG Xi-He,WU Xin-Tao.Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a New Zinc Carboxylate-phosphonate: [Zn3(O3PCH(CH3)COO)2(H2O)][J].Chinese Journal of Structural Chemistry,2006,25(11):1397-1401. |
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| Authors: | LAI Zhu-Zhi FU Rui-Biao SHENG Tian-Lu LI Ya-Min HUANG Xi-He WU Xin-Tao |
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| Institution: | 1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;Graduate School of the Chinese Academy of Sciences, Beijing 100039, China
2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on theStructure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
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| Abstract: | A new carboxylate-phosphonate, Zn3(O3PCH(CH3)COO)2(H2O)] 1, has been success- fully synthesized by hydrothermal technique and characterized by X-ray single-crystal structure analysis, elemental analysis and infrared spectroscopy. It crystallizes in monoclinic, space group P21/c with a = 4.9521(5), b = 21.953(3), c = 13.2266(18) (A), β = 100.704(2)o, V = 1412.9(3) (A)3, Z = 4, Mr ＝ 516.19, Dc = 2.427 g/cm3, F(000) = 1016, μ(MoKα) = 5.332 mm-1 and T = 293(2) K. The final R = 0.0605 and wR = 0.1354 for 2957 observed reflections with Ⅰ ＞2σ(Ⅰ). The thermogravimetric analysis (TGA) and fluorescent measurement have been done. The structure of compound 1 is a 3D open framework with 32-atom channels. |
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| Keywords: | hydrothermal synthesis single crystal carboxlate-phosphonate open framework |
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