Synthesis and structure of the cluster Fe2Mo2(μ3-Se)(μ3-AsMe)(μ3-Co)(μ-Co)(Co)5(η5-Cp)2 |
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| Authors: | S N Konchenko A V Virovets P A Petrov S V Tkachev |
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| Institution: | (1) Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090 Novosibirsk, Russian Federation |
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| Abstract: | The reaction of (Et4N)2Fe3(μ3-Se)(Co)9] with MeAsI2 afforded the Fe3(μ3-Se)(μ3-AsMe)(Co)9] cluster, which was characterized by1H NMR and IR spectroscopy and elemental analysis. The reaction of the resulting compound with the dimeric, complex η5-CpMo(CO)3#x005D;2 inm-xylene upon refluxing gave the heterometallic cluster Fe2Mo2(μ3-Se)(μ3-AsMe)(μ3-Co)(μ-Co)(Co)5(η5-Cp)2, whose structure was established by X-ray diffraction analysis.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 996–998, May, 1999. |
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| Keywords: | iron molybdenum selenium arsenic carbonyl clusters synthesis 1H NMR spectra X-ray diffraction analysis |
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