| Hydrothermal Synthesis and Structure of One New Polyoxottmgsate [Ni(trien)]_4[Ni_4(H_2O)_2(HPW_9O_(34))_2]·4H_2O |
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| 作者单位： | ZHAO Dan(State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structre of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China;Biology and Chemistry Engineering Department);ZHENG Shou-Tian,YANG Guo-Yu(State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structre of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China) |
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| 基金项目： | the National Natural Science Fund for Distinguished Young Scholars of China，the 973 Program，the NSF of Fujian Province，the NNSFC，the Research Foundation of Education Bureau of Fujian Province |
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| 摘 要： | One new sandwich-type tetra-nickel substituted polyoxotungsate,Ni(trien)]_4-Ni_4(H_2O)_2(HPW_9O_(34))_2]·4H_2O(1,trien=triethylenetetramine),has been hydrothermally synthesized and characterized by IR,elemental analysis,TGA,and single-crystal X-ray diffraction analysis.Crystal data for l:triclinic,space group Pī with a=13.279(3),b.13.816(3),C=14.494(4)(A),α=95.403(1),β=113.173(4),γ=93.809(3)°,V=2418.0(10)(A)~3,Z=1 and Dc=3.861g/cm~3.X-ray crystallographic study shows that compound 1 is a relatively rare inorganic-organic hybrid polyoxo tungstate constructed from sandwich Ni-substituted polyoxo-anions and nickel complexes.
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