Electrochemical iodination of C-methyl derivatives of dodecahydro-7,8-dicarba-nido-undecaborate anion |
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| Authors: | D A Rudakov V L Shirokii V I Potkin E A Dikusar V I Bragin P V Petrovskii I B Sivaev V I Bregadze A V Kisin |
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| Institution: | (1) Institute of Physical Organic Chemistry, Belarussian Academy of Sciences, Minsk, 220072, Belarus;(2) Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813, Russia;(3) State Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, Russia |
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| Abstract: | By electrochemical iodination of potassium 7-methyl-7,8-dicarba-nido-undecaborate and potassium 7,8-dimethyl-7,8-dicarba-nido-undecaborate, their monoiodine derivatives (extracted as tetramethylammonium salts) are synthesized. Their structure is confirmed by NMR and IR spectra and also by elemental analysis data. |
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| Keywords: | carboranes dicarba-nido-undecaborate iodination electrochemistry boron-neuron-capture therapy of cancer |
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