| STUDIES ON SYNTHESIS, STRUCTURE AND PROPERTIES OF THE CRYSTAL OF TRIADIC COMPLEX {Mo[S_2CN(C_2H_5)_2]_4}~( 1){FeCl_4}~(-1){C_6H_5CH_2SSCH_2C_6H_5} |
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| 作者姓名： | 徐丽娟 张致贵 牛淑云 李淑芹 |
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| 作者单位： | Nitrogen Fixation Group of Department of Chemistry，Jilin University，Changchun，Nitrogen Fixation Group of Department of Chemistry，Jilin University，Changchun，Nitrogen Fixation Group of Department of Chemistry，Jilin University，Changchun，Nitrogen Fixation Group of Department of Chemistry，Jilin University，Changchun |
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| 摘 要： | In this paper, a new complex {MoS_2CN(C_2H_5)_2]_4}~( 1){FeCl}~(-1){C_6H_5CH_2SSCH_2C_6H_5} is syn-thesized by the reaction of MoCl_5, FeCl_3, PhCH_2SH and diethyldithiocarbamate (DTC)in MeOH. The complex is characterized by X-ray, IR, UV-visible, reflection spectra, themeasurements of magnetic susceptibility, differential thermal and elemental analyses. The crystal of triadic complex containing multi-bond species is quite stable and rare.
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