| Crystal Structure of a Cu（Ⅱ） Coordination Polymer： [Cu（IP）（TBZH）]2n （TBZH = Thiabendazole,IP = Isophthalic Acid） |
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| 引用本文： | 王家军,吕明,孙亚明,崔运成,黄艳菊,李传碧,高广刚. Crystal Structure of a Cu（Ⅱ） Coordination Polymer： [Cu（IP）（TBZH）]2n （TBZH = Thiabendazole,IP = Isophthalic Acid）[J]. 结构化学, 2009, 28(4): 434-438 |
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| 作者姓名： | 王家军 吕明 孙亚明 崔运成 黄艳菊 李传碧 高广刚 |
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| 作者单位： | WANG Jia-Jun,LV Ming,CUI Yun-Cheng,HUANG Yan-Jua,GAO Guang-Gang(Chemistry Department of Jilin Normal University,Siping 136000,China);SUN Ya-Ming,LI Chuan-Bi(Physics Department of Jilin Normal University,Siping 136000,China) |
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| 基金项目： | supported by Siping Sci-tech Development Planning Project (No. 2005012) |
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| 摘 要： | The structure of a copper（Ⅱ） polymer, [Cu（IP）（TBZH）]2n 1 （TBZH = thiabendazole, IP = isophthalic acid）, has been determined by X-ray crystallography and characterized by elemental analysis, IR spectrum and thermogravimetric analysis. It crystallizes in the monoclinic system, space group P21/n with a = 11.76, b = 10.41, c = 14.08A^°, β = 104.80°, V= 1666.0（3）A^°^3, Z = 4, Mr= 428.90, Dc= 1.710 g/cm^3, F（000） = 868,μ = 1.468 mm^-1 and S = 1.001. The 2-D layered gridding architecture of 1 is constructed from isophthalic acid and binuclear copper atoms. Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to a supramolecular structure.
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| 关 键 词： | 间苯二甲酸 配位聚合物 知识产权 晶体结构 铜原子 噻菌灵 X射线晶体学 超分子结构 |
Crystal Structure of a Cu(Ⅱ)Coordination Polymer:[Cu(IP)(TBZH)]2n(TBZH=Thiabendazole,IP=Isophthalic Acid) |
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| WANG Jia-Jun,LV Ming,SUN Ya-Ming,CUI Yun-Cheng,HUANG Yan-Jua,LI Chuan-Bi,GAO Guang-Gang. Crystal Structure of a Cu(Ⅱ)Coordination Polymer:[Cu(IP)(TBZH)]2n(TBZH=Thiabendazole,IP=Isophthalic Acid)[J]. Chinese Journal of Structural Chemistry, 2009, 28(4): 434-438 |
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| Authors: | WANG Jia-Jun LV Ming SUN Ya-Ming CUI Yun-Cheng HUANG Yan-Jua LI Chuan-Bi GAO Guang-Gang |
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| Affiliation: | 1. Chemistry Department of Jilin Normal University,Siping 136000,China
2. Physics Department of Jilin Normal University,Siping 136000,China |
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| Abstract: | The structure of a copper(Ⅱ)polymer,[Cu(IP)(TBZH)]2n 1(TBZH=thiabendazole,IP=isophthalic acid),has been determined by X-ray crystallography and characterized by elemental analysis,IR spectrum and thermogravimetric analysis.It crystallizes in the monoclinic system,space group P21/n with a=11.76,b=10.41,c=14.08(A),β=104.80°,V=1666.0(3)(A)3,Z =4,Mr=428.90,Dc=1.710 g/cm3,F(000)=868,μ=1.468 mm-1 and S=1.001.The 2-D layered gridding architecture of 1 is constructed from isophthalic acid and binuclear copper atoms.Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to a supramolecular structure. |
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| Keywords: | thiabendazole single-crystal structure |
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