| Crystal Structure of a Cu（Ⅱ） Coordination Polymer： [Cu（IP）（TBZH）]2n （TBZH = Thiabendazole,IP = Isophthalic Acid） |
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| 引用本文： | 王家军,吕明,孙亚明,崔运成,黄艳菊,李传碧,高广刚.Crystal Structure of a Cu（Ⅱ） Coordination Polymer： [Cu（IP）（TBZH）]2n （TBZH = Thiabendazole,IP = Isophthalic Acid）[J].结构化学,2009,28(4):434-438. |
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| 作者姓名： | 王家军 吕明 孙亚明 崔运成 黄艳菊 李传碧 高广刚 |
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| 作者单位： | WANG Jia-Jun,LV Ming,CUI Yun-Cheng,HUANG Yan-Jua,GAO Guang-Gang(Chemistry Department of Jilin Normal University,Siping 136000,China);SUN Ya-Ming,LI Chuan-Bi(Physics Department of Jilin Normal University,Siping 136000,China)
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| 基金项目： | supported by Siping Sci-tech Development Planning Project (No. 2005012) |
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| 摘 要： | The structure of a copper（Ⅱ） polymer, Cu（IP）（TBZH）]2n 1 （TBZH = thiabendazole, IP = isophthalic acid）, has been determined by X-ray crystallography and characterized by elemental analysis, IR spectrum and thermogravimetric analysis. It crystallizes in the monoclinic system, space group P21/n with a = 11.76, b = 10.41, c = 14.08A^°, β = 104.80°, V= 1666.0（3）A^°^3, Z = 4, Mr= 428.90, Dc= 1.710 g/cm^3, F（000） = 868,μ = 1.468 mm^-1 and S = 1.001. The 2-D layered gridding architecture of 1 is constructed from isophthalic acid and binuclear copper atoms. Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to a supramolecular structure.
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| 关 键 词： | 间苯二甲酸 配位聚合物 知识产权 晶体结构 铜原子 噻菌灵 X射线晶体学 超分子结构 |
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