Ionic liquid synergistic cation-exchange system for the selective extraction of lanthanum(III) using 2-thenoyltrifluoroacetone and 18-crown-6. |
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| Authors: | Naoki Hirayama Hiroyuki Okamura Keiji Kidani Hisanori Imura |
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| Affiliation: | Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University. hirayama@cacheibm.s.kanazawa-u.ac.jp |
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| Abstract: | A novel synergistic extraction system was investigated for the possible selective separation of light lanthanoids using an ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, as an extraction solvent and 2-thenoyltrifluoroacetone and 18-crown-6 as extractants. Trivalent lanthanum was efficiently extracted as a cationic ternary complex by the cation-exchange process, whereas europium and lutetium showed relatively low extractability without forming respective ternary complexes. This result is thought to originate in a size-fitting effect of 18-crown-6 to lanthanum and the unique nature of the ionic liquid as a chelate extraction solvent. |
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