Prostanoids: LXXXVI. Synthesis and Reductive Transformations of 2-Chloro-4,4-ethylenedioxy-3-phenylsulfanyl-2-cyclopentenone |
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Authors: | Ivanova N. A. Khusainova A. A. Shangiraeva F. G. Akhmetvaleev R. R. Miftakhov M. S. |
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Affiliation: | (1) Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054 Bashkortostan, Russia |
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Abstract: | The reduction of 2-chloro-4,4-ethylenedioxy-3-phenylsulfanyl-2-cyclopentenone with sodium tetra-hydridoborate in ethanol yields 3-chloro-4-hydroxy-2-phenylsulfanyl-2-cyclopentenone, while with the use of lithium aluminum hydride in tetrahydrofuran or the system Zn/NH4Cl in methanol products of more profound reduction are obtained. |
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