Mizoroki-Heck reaction of (1-fluorovinyl)methyldiphenylsilane with aryl iodides |
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| Authors: | Hirotaki Kensuke Hanamoto Takeshi |
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| Affiliation: | Department of Chemistry and Applied Chemistry, Saga University, Honjyo-machi 1, Saga 840-8502, Japan. |
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| Abstract: | The Mizoroki-Heck reaction of (1-fluorovinyl)methyldiphenylsilane with a variety of aryl iodides was accomplished under the conditions composing Pd(OAc)(2), Ag(2)CO(3) and MS 4 ? in 1,4-dioxane to give the corresponding (E)-β-aryl-(α-fluorovinyl)methyldiphenylsilanes with excellent stereoselectivity. |
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