Dioxygenase-catalysed dihydroxylation of arene cis-dihydrodiols and acetonide derivatives: a new approach to the synthesis of enantiopure tetraoxygenated bioproducts from arenes |
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| Authors: | Boyd Derek R Sharma Narain D Belhocine Tayeb Malone John F McGregor Stuart Allen Christopher C R |
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| Affiliation: | School of Chemistry and Chemical Engineering, Belfast, UKBT9 5AG. dr.boyd@qub.ac.uk |
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| Abstract: | cis-Dihydrodiols of anthracene and benz[a]anthracene, and acetonide derivatives of the cis-dihydrodiols of benzene, fluorobenzene, biphenyl and phenanthrene have been identified as substrates for dioxygenase enzymes, yielding the corresponding enantiopure arene bioproducts, bis(cis-dihydrodiol)s and cis-diol acetonides respectively. |
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