Electrocatalytic transformation of dialkyl malonates and arylidene- or alkylidenemalononitriles into dialkyl esters of 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylic acids |
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| Authors: | M N Elinson S K Feducovich T A Zaimovskaya A N Vereshchagin S V Gorbunov G I Nikishin |
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| Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation;(2) A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 119991 Moscow, Russian Federation |
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| Abstract: | Electrolysis of alcoholic solutions of dialkyl malonates and arylidene- or alkylidenemalononitriles in the presence of NaBr
in an undivided cell gave dialkyl esters of 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylic acids in 60–90% yields.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1547–1552, July, 2005. |
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| Keywords: | electrolysis electrocatalytic transformation dialkyl malonates arylidenemalononitriles alkylidenemalononitriles mediators substituted cyclopropanes |
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