Kinetics and mechanism of the thermal decomposition of 1-bromo-4-nitroxymethylcubane |
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| Authors: | V. V. Dubikhin V. G. Prokudin L. D. Nazina L. B. Romanova L. T. Eremenko G. M. Nazin |
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| Affiliation: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia |
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| Abstract: | The thermal decomposition kinetics of 1-bromo-4-nitroxymethylcubane in the liquid phase is typical of C-ONO2 bond heterolysis, which occurs if the nitro ester has a strong donor substituent. A comparison between 1-bromo-4-nitroxymethylcubane and tert-butyl nitrate shows that bromocubyl is close to the tert-butyl group in induction properties and cubyl itself is a stronger donor than this group. |
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