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多级结构还原氧化石墨烯包覆的钴铁氧体的合成及电化学性能
引用本文:张彬,张一波,杨向光. 多级结构还原氧化石墨烯包覆的钴铁氧体的合成及电化学性能[J]. 应用化学, 2014, 31(12): 1447-1452. DOI: 10.3724/SP.J.1095.2014.40101
作者姓名:张彬  张一波  杨向光
作者单位:(1.中国科学院长春应用化学研究所绿色化学与过程实验室 长春 130022;2.中国科学院研究生院 北京 100049)
基金项目:吉林省科技厅资助项目(20116009)~~
摘    要:以水滑石为前驱体合成微米花/纳米片多级结构过渡金属复合氧化物CoFe2O4,一种高性能锂离子电池负极材料。 通过X射线衍射仪(XRD)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)等技术手段对其进行结构表征,发现得到的复合氧化物为单一晶相,且具有多级结构。 电化学性能测试表明,得到的负极材料具有高比容量和倍率性能。 通过还原氧化石墨烯(rGO)对CoFe2O4进行表面包覆制备CoFe2O4/rGO,其循环稳定性得到大幅度提高。

关 键 词:锂离子电池  负极材料  复合氧化物  多级结构  电化学性能  
收稿时间:2014-03-28
修稿时间:2014-05-12

Synthesis and Electrochemical Performance of Reduced Graphene Oxide Coated Cobalt Iron Oxide with Hierarchical Structure
ZHANG Bin;ZHANG Yibo;YANG Xiangguang. Synthesis and Electrochemical Performance of Reduced Graphene Oxide Coated Cobalt Iron Oxide with Hierarchical Structure[J]. Chinese Journal of Applied Chemistry, 2014, 31(12): 1447-1452. DOI: 10.3724/SP.J.1095.2014.40101
Authors:ZHANG Bin  ZHANG Yibo  YANG Xiangguang
Affiliation:(1.Laboratory of Green Chemistry and Process,Changchun Institute of ;Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China;2.University of Chinese Academy of Sciences,Beijing 100049,China)
Abstract:Binary transition metal oxide CoFe2O4 as a high capacity anode material for lithium-ion batteries with the microflower/nanosheet hierarchical structure was synthesized by layered double hydrotalcite-like precursors. The CoFe2O4 and reduced graphene oxide(rGO)coated CoFe2O4(CoFe2O4/rGO) materials were characterized by powder X-ray diffraction(XRD), scanning electron microscope(SEM), transmission electron microscope(TEM) techniques. The electrochemical performances of the CoFe2O4 and CoFe2O4/rGO electrodes were examined in terms of cyclic voltammetry and discharge/charge profiles. The electrodes exhibit high capacity and rate capacity. Furthermore, the cyclic performance of CoFe2O4/rGO electrode is better than that of the CoFe2O4 electrode.
Keywords:lithium-ion batteries  anode materials  binary metal oxides  hierarchicalstructure  electrochemical performance
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