| 配位聚合物 |
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| 引用本文： | 张琳萍,侯红卫,樊耀亭,程凤宏.配位聚合物[J].无机化学学报,2000,16(1):1-12. |
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| 作者姓名： | 张琳萍 侯红卫 樊耀亭 程凤宏 |
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| 作者单位： | 郑州大学化学化工学院,郑州,450052 |
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| 基金项目： | 国家自然科学基金资助项目 !(No.29941001) |
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| 摘 要： | 配位聚合物是通过过渡金属和有机配体的自组装而形成的 ,它结合了复合高分子和配位化合物两者的特点 ,表现出其独特的性质 ,在非线性光学材料、磁性材料、超导材料及催化等诸多方面都有极好的应用前景。本文根据有机配体种类的不同 ,将配位聚合物分为五大类 ,以便于对它们进行研究。1.含氮杂环类配体的配位聚合物 ;2.含CN有机配体的配位聚合物 ;3.含氧有机配体的配位聚合物 ;4.通过两种配体与一种金属组装成的配位聚合物 ;5.两种以上的金属与相应的配体组装而成的配位聚合物。
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| 关 键 词： | 配位化合物 聚合物 自组装 过渡金属 有机配件 |
| 收稿时间： | 7/5/1999 12:00:00 AM |
| 修稿时间： | 1999/8/10 0:00:00 |
Coordination Polymers |
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| ZHANG Lin-Ping,HOU Hong-Wei,FAN Yao-Ting and CHENG Feng-Hong.Coordination Polymers[J].Chinese Journal of Inorganic Chemistry,2000,16(1):1-12. |
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| Authors: | ZHANG Lin-Ping HOU Hong-Wei FAN Yao-Ting and CHENG Feng-Hong |
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| Institution: | Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052 and Department of Chemistry, Zhengzhou University, Zhengzhou 450052 |
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| Abstract: | Coordination polymers are a kind of novel supramolecular compounds, formed by the self assembly of transition metals and organic ligands. They represent a new and active area of coordination chemistry because of their special roles in magnetic materials, non linear optical materials, catalysis, etc. In order to undertake further research, we classify the existing coordination polymers into five categories: 1. heterocyclic coordination polymers; 2. CN containing coordination polymers; 3. oxygen ligand containing coordination polymers; 4. coordination polymers containing two kinds of organic ligands; 5. coordination polymers with two kinds of metals. |
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| Keywords: | coordination compounds polymers self assembly |
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