子的配分函数——物理意义与作用

讨论怎样理解子的配分函数的物理意义,以及它和系统的配分函数在计算热力学函数中的作用,指出它既不是系统的广延性质,也不是系统的强度性质,只是联系系统热力学函数与微观信息的纽带。

The Physical Significance and the Role of the Molecular Partition Function

We discussed the physical meaning of the molecular partition function, and the role of both the molecular partition function and the partition function of the system in the calculation of the thermodynamic properties.It was shown that the molecular partition function is neither an extensive property nor an intensive one, but only a tie to connect the thermodynamic properties with the microscopic information of the system.